1. TIBCO BusinessWorks™ Palette Reference, Version 6.8, "SOAP Palette" section, "SOAP Request Reply" subsection: "The SOAP Request Reply activity is used to invoke a specific operation of a web service. The activity is a client that sends a request to the web service and waits for a response." (This document explicitly states the purpose of the activity is to invoke a web service).
2. TIBCO BusinessWorks™ Palette Reference, Version 6.8, "REST & JSON Palette" section, "Invoke API" subsection: "The Invoke API activity is used to invoke a REST API. The activity uses a Swagger file that defines the REST API to configure the request and response." (This clarifies that Invoke API is for REST, not general web services).
3. TIBCO BusinessWorks™ Palette Reference, Version 6.8, "General Activities Palette" section, "Invoke" subsection: "The Invoke activity is used to invoke a subprocess." (This confirms the activity is for internal process calls).